The Periodic Law
The properties of the elements are a periodic function of their atomic numbers
Vertical columns are called groups or families. Horizontal rows are called periods.
Group IA - Alkali Metals
Group IIA - Alkaline Earth Metals
Group VIIA - Halogens
Group VIIIA - Nobel Gases
Groups IA --> VIIIA Representative Elements
Groups IB --> VIIIB Transition Elements
Elements 58 --> 70 Lanthanide Elements
Elements 90 --> 102 Actinide Element
The Lanthanides and Actinides are both called Inner Transition Elements
An electron configuration indicates how electrons fill into subshells of a given atom. A "ground state" electron configuration illustrates electrons occupying the lowest available energy levels.
The sequence of subshell filling in not as straight forward as one might expect. Subshells in a given shell do not all always fill before some electrons are filled into the next higher shell.
The order of filling for electrons in a ground state electron configuration is illustrated by the Aufbau (German, to build) diagram.
Sample Electron Configuration
H 1s1
Li 1s22s1
Na 1s22s22p63s1
K 1s22s22p63s23p64s1
Rb 1s22s22p63s23p64s23d104p65s1
Na 1s22s22p63s1
Mg 1s22s22p63s2
Al 1s22s22p63s23p1
Si 1s22s22p63s23p2
P 1s22s22p63s23p3
S 1s22s22p63s23p4
Cl 1s22s22p63s23p5
Ar 1s22s22p63s23p6
K 1s22s22p63s23p64s1
Ca 1s22s22p63s23p64s2
Sc 1s22s22p63s23p64s23d1
Ti 1s22s22p63s23p64s23d2
V 1s22s22p63s23p64s23d3
Hund's Rule
When electrons occupy orbitals of equal energy (same shell and subshell)
they fill into the subshell remaining unpaired to the maximum extent possible
with their spins paired.
p4
Px Py Pz
d4
d7
A diamagnetic atom has no unpaired electrons and is slightly repelled by a magnetic field. A paramagnetic atom has at least one unpaired electron and is slightly attracted by a magnetic field. Ferromagnetism is a stronger form of paramagnetism.
One can observe that elements with similar chemistry, placed in groups by Mendeleev, have similar outer shell electron configuration.
Regularly repeating chemical properties, as observed in the Periodic Law, are a result of regularly repeating similar electron configurations.
The distinguishing electron for an element in the last electron added when following the Aufbau principle.
Electron configuration with f sublevels.
64Gd 1s22s22p63s23p64s23d104p65s24d105p66s24f8
Short hand for electron configurations using the noble gas in the previous
period.
Ne 1s22s22p6
P 1s22s22p63s23p3
P [Ne] 3s23p3
Ar 1s22s22p63s23p6
Ti [Ar] 4s23d2
In general metals have good thermal and electrical conductivity, are malleable, lustrous, ductile and form positive ions. Nonmetals tend to opposite properties.
Metalloids have properties intermediate between metals and nonmetals.
For example Si, Ge, Sb, are useful for making semiconductors.